Reactive geochemical transport modeling of hydrothermal dolomite fronts: The case of Marjaba dolomite front (Jurassic,Lebanon)     

F.H. Nader  D. Garcia  T. Parra  R. Swennen  R.M. Ellam  S.A. Gleeson 《Journal of Geochemical Exploration》2009

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Fluid flow reconstruction in karstified Panormide platform limestones (north-central Sicily): Implications for hydrocarbon prospectivity in the Sicilian fold and thrust belt     

B. Dewever  I. Berwouts  R. Swennen  L. Breesch  R.M. Ellam 《Marine and Petroleum Geology》2010,27(4):939-958

Diagenetic analysis based on field and petrographic observations, isotope and microthermometric data was used to reconstruct the fluid flow history of the Cretaceous shallow water limestones from the Panormide platform exposed in north-central Sicily. Analysis focused on diagenetic products in cavities and dissolution enlarged fractures of the karstified limestones that occur just below a regional unconformity. The fluid flow history could be broken down into five stages that were linked to the kinematic and burial history of the region. (1) Petrography (zoned cathodoluminescence and speleothem textures) and stable isotopes (6.5 < δ¹⁸O_V-PDB < ?3.5‰ and 0 < δ¹³C_V-PDB < ?14‰) indicate that the earliest calcite phase was associated with karstification during emergence of the platform. Limestone dissolution at this stage is important with regard to possible reservoir creation in the Panormide palaeogeographic domain. (2) Fine-grained micrite sedimentation, dated as latest Cretaceous by nannopalaeontology and its ⁸⁷Sr/⁸⁶Sr isotope ratio (0.7078), marks replacement by marine fluids during subsequent submergence of the karstified platform. (3) The following calcite cement was still precipitated by marine-derived fluids (?7.0 < δ¹⁸O_V-PDB < ?5.0‰ and ?3.0 < δ¹³C_V-PDB < 0.5‰/T_m = ?2 to ?5 °C), but at increasingly higher temperatures (T_h = 60–120 °C). This has been interpreted as precipitation during Oligocene foredeep burial. (4) Hot (T_h = 130–180 °C), low saline (T_m < ?2.5 °C) fluids with increasingly higher calculated δ¹⁸O_SMOW signatures (+6 to +14‰) subsequently invaded the karst system. These fluids most likely migrated during fold and thrust belt development. The low salinity and relatively high δ¹⁸O_SMOW signatures of the fluids are interpreted to be the result of clay dewatering reactions. The presence of bitumen and associated fluorite with hydrocarbon inclusions at this stage in the paragenesis constrains the timing of oil migration in the region. (5) Finally, high saline fluids with elevated ⁸⁷Sr/⁸⁶Sr (0.7095–0.7105) signatures invaded the karst system. This last fluid flow event was possibly coeval with localized dolomitization and calcite cementation along high-angle faults of Pliocene age, as suggested by identical radiogenic signatures of these diagenetic products.  相似文献   

Water extractable material from the B horizon of a contiguous aspen and birch forest in interior Alaska     

Rudy Candler 《Organic Geochemistry》1985,8(1):127

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A detailed study of the 5-Hz quasi-periodic oscillations in the bright X-ray transient and black hole candidate GRS 1739–278     

Rudy Wijnands †  Mariano Méndez  Jon M. Miller  Jeroen Homan 《Monthly notices of the Royal Astronomical Society》2001,328(2):451-460

We present a detailed study of the 5-Hz quasi-periodic oscillation (QPO) recently discovered in the bright X-ray transient and black hole candidate (BHC) GRS     (Borozdin & Trudolyubov) during a Rossi X-ray Timing Explorer observation taken on 1996 March 31. In total 6.6 ksec of on-source data were obtained, divided in two data sets of 3.4 and 3.2 ksec which were separated by ∼2.6 ksec. The 5-Hz QPO was only present during the second data set. The QPO increased in strength from below 2 per cent rms amplitude for photon energies below 4 keV to ∼5 per cent rms amplitude for energies above 10 keV. The soft QPO photons (below 5 keV) lagged the hard ones (above 10 keV) by almost 1.5 rad. Besides the QPO fundamental, its first overtone was detected. The strength of the overtone increased with photon energy (from < 2 per cent rms below 5 keV to ∼8 per cent rms above 10 keV). Although limited statistics did not allow for an accurate determination of the lags of the first overtone, indications are that also for this QPO the soft photons lagged the hard ones. When the 5-Hz QPO was not detected (i.e., during the first part of the observation), a broad noise component was found for photon energies below 10 keV but it became almost a true QPO (with a Q value of ∼1.9) above that energy, with a frequency of ∼3 Hz. Its hard photons preceded the soft ones in a way reminiscent of the 5-Hz QPO, strongly suggesting that both features are physically related. We discuss our finding in the framework of low-frequency QPOs and their properties in BHCs.  相似文献   

Development of secondary porosity in the Fairholme carbonate complex (southwest Alberta, Canada)   总被引：4，自引：0，他引：4  

Veerle Vandeginste  Rudy Swennen  Sarah A. Gleeson  Rob M. Ellam  Kirk Osadetz  Franois Roure 《Journal of Geochemical Exploration》2006,89(1-3):394

Because of their economic importance as hydrocarbon reservoirs, the Upper Devonian dolomitized carbonate reefs in southwest Alberta have been the subject of several studies. Still, there is no consensus on the process of matrix dolomitization and furthermore, the process of vug development is not often addressed. The studied outcrops show features of an early diagenetic matrix-selective dolomitization by a Late Devonian seawater-derived fluid. Seepage reflux dolomitization combined with latent reflux is proposed, which best explains most chemical characteristics. The cements in the vugs are precipitated from warm saline, ⁸⁷Sr-enriched fluids and testify to thermogenic sulphate reduction based on the presence of sulphur, CO₂ and H₂S in inclusions, relatively high homogenization temperatures and depleted δ¹³C values, which sets constraints on the timing of vug formation. Secondary porosity may be created by the mixing of formation water with a tectonically and topographically driven fluid and by the dissolution of anhydrite nodules.  相似文献   

Paragenesis of Cretaceous to Eocene carbonate reservoirs in the Ionian fold and thrust belt (Albania): relation between tectonism and fluid flow   总被引：1，自引：0，他引：1  

M. Van Geet  R. Swennen  C. Durmishi†  F. Roure‡  PH. Muchez 《Sedimentology》2002,49(4):697-718

ABSTRACT This paper examines the diagenetic history of dual (i.e. matrix and fracture) porosity reservoir lithologies in Cretaceous to Eocene carbonate turbidites of the Ionian fold and thrust belt, close to the oil‐producing centre of Fier–Ballsh (central Albania). The first major diagenetic event controlling reservoir quality was early cementation by isopachous and syntaxial low‐Mg calcite. These cements formed primarily around crinoid and rudist fragments, which acted as nucleation sites. In sediments in which these bioclasts are the major rock constituent, this cement can make up 30% of the rock volume, resulting in low effective porosity. In strata in which these bioclasts are mixed with reworkedmicrite, isopachous/syntaxial cements stabilized the framework, and matrixporosity is around 15%. The volumetric importance of these cements, their optical and luminescence character (distribution and dull orange luminescence) and stable isotopic signal (δ¹⁸O and δ¹³C averaging respectively; ?0·5‰ VPDB and +2‰ VPDB) all support a marine phreatic origin. Within these turbidites and debris flows, several generations of fractures alternated with episodes of cementation. A detailed reconstruction of this history was based on cross‐cutting relationships of fractures and compactional and layer‐parallel shortening (LPS) stylolites. The prefolding calcite veins possess orange cathodoluminescence similar to that of the host rock. Their stable isotope signatures (δ¹⁸O of ?3·86 to ?0·85‰ VPDB and δ¹³C of – 0·14 to + 2·98‰ VPDB) support a closed diagenetic rock‐buffered system. A similar closed system accounts for the selectively reopened and subsequently calcite‐cemented LPS stylolites (δ¹⁸O of ?1·81 to ?1·14‰ VPDB and δ¹³C of +1·52 to +2·56‰ VPDB). Within the prefolding veins, brecciated host rock fragments and complex textures such as crack and seal features resulted from hydraulic fracturing. They reflect expulsion of overpressured fluids within the footwall of the frontal thrusts. After folding and thrust sheet emplacement, some calcite veins are still rock buffered (δ¹⁸O of ?0·96 to +0·2‰ VPDB and δ¹³C of +0·79 to +1·37‰ VPDB), whereas others reflect external (i.e. extraformational) and thus large‐scale fluid fluxes. Some of these veins are linked to basement‐derived fluid circulation or originated from fluid flow along evaporitic décollement horizons (δ¹⁸O around +3·0‰ VPDB and δ¹³C around +1·5‰ VPDB). Others are related to the maturation of hydrocarbons in the system (δ¹⁸O around ?7·1‰ VPDB and δ¹³C around +9·3‰ VPDB). An open joint system reflecting an extensional stress regime developed during or after the final folding stage. This joint system enhanced vertical connectivity. This open joint network can be explained by the high palaeotopographical position and the folding of the reservoir analogue within the deformational front. The joint system is pre‐Burdigalian in age based upon a dated karstified discordance contact. Sediment‐filled karst cavity development is linked to meteoric water infiltration during emergence of some of the structures. Despite its sediment fill, the karst network is locally an important contributor to reservoir matrix porosity in otherwise tight lithologies. Development of secondary porosity along bed‐parallel and bed‐perpendicular (i.e. layer‐parallel shortening) stylolites is interpreted as a late‐stage diagenetic event associated with migration of acidic fluids during hydrocarbon maturation. Development of porosity along the LPS system enhanced the vertical reservoir connectivity.  相似文献   

Pollen analysis of some mid-Pleistocene interglacial lagoonal sediments from southern Delaware     

Rudy J. Nickmann  James M. Demarest 《Quaternary Research》1982,17(1):93-104

Results of pollen analysis on lagoonal sediments from southern Delaware, dated at 500,000–1,000,000 yr B.P. by amino acid racemization, are presented. Three pollen zones are identified in sediments that were deposited during the final stage of an interglacial cycle. A closed forest of mixed conifer-deciduous trees dominated by Tsuga, Pinus, Fagus, Liquidambar, and Quercus is recorded in the basal zone (Zone I). The inferred climate at this time was temperate and moist. A probable lowering of sea level during the deposition of Zone II exposed large areas in the surrounding estuaries and tidal flats which were colonized by marsh and bog plant taxa. Zone III is characterized by Pinus, Quercus, and Picea pollen. A scrub oak-pine association may have been favored on the coarse sandy soils of the Delmarva Peninsula at this time because of a drop in the local water table. The inferred climate during this interval was colder and probably drier than in Zone I.  相似文献   

X-ray timing behaviour of Cygnus X-2 at low intensities     

Erik Kuulkers  Rudy Wijnands  Michiel van der Klis 《Monthly notices of the Royal Astronomical Society》1999,308(2):485-492

It is known that the overall (mean) intensity of the low-mass X-ray binary Cyg X-2 varies on time-scales from a day to months, independently of the variations on time-scales of hours to a day by which the source moves between the horizontal, normal and flaring branches.
We present RXTE PCA observations of Cyg X-2, taken when its overall intensity was near its lowest values, in 1996 October and 1997 September. For the first time we perform a study of the fast timing behaviour at such low intensities. During the 1996 October observations, the source was in the left part of the horizontal branch, and during the 1997 September observations was most likely in the lower parts of the normal branch and flaring branch.
We find that the properties of the very low-frequency noise during the 1997 September observations are consistent with a monotonic decrease in its strength and power-law index as a function of overall intensity. In contrast, the strength of the ∼6 Hz normal branch quasi-periodic oscillations does not vary monotonically with overall intensity. They are strongest at medium overall intensity and weaker both when the overall intensity is low and when the overall intensity is high.  相似文献   

Appropriate sampling strategy and analytical methodology to address contamination by industry. Part 2: Geochemistry and speciation analysis     

Aurela Shtiza  Rudy Swennen 《Central European Journal of Geosciences》2011,3(1):53-70

The degree of contamination in soils, sediments and dusts can be assessed based on knowledge of a variety of factors, such as industrialization, type of contaminants, deposition conditions, contamination-control techniques, along with the characteristics of the recipient environmental compartments, which include pathways for contamination transport, depth of infiltration, and degree of groundwater contamination. The impact of contaminants also depends on the quantity, mobility and speciation of contaminants/wastes as well as on the sensitivity of the recipient compartments. With sufficient knowledge of these factors, a number of conclusions can be drawn concerning the status of contamination in industrialized areas. This literature review aims to scrutinize some of the methods used to analyse the occurrence, speciation, mobility, bioavailability and likely the toxic effects of contaminants in the environment.  相似文献   

Awards presented by the International Association of Sedimentologists at the 18th International Sedimentological Congress,Mendoza, Argentina
Citation of John Bridge for the Sorby Medal     

Jim Best  Rudy Slingerland 《Sedimentology》2011,58(3):824-826

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